Product ID:ECCOSLIP 122S (AEROSOL)
MSDS Date:04/22/1993
FSC:6850
NIIN:01-028-4642
MSDS Number: BYTBD

EMERSON & CUMING,INC., DIV OF W.R.GRACE AND CO.

55 HAYDEN AVE
LEXINGTON, MA 02173
US

Emergency Phone: 800-424-9300(CHEMTREC)/202-483-7616

Info Phone: 800-225-1936/617-861-6600

Preparer: DAVID HAAS

Cage: DO244

EMERSON & CUMING,INC., DIV OF W.R.GRACE AND CO.

WOBURN, MA 01180 US

Telephone: 800-225-1936

Cage: 0JMR7

METHYLENE CHLORIDE (SARA 313) (CERCLA)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 45-55%

OSHA PEL 500 PPM; Z-2

ACGIH TLV: 50 PPM, A2; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

DICHLORODIFLUOROMETHANE (SARA 313) (CERCLA) (FREON 12)

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: 45-55%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SILICONE RESIN

Fraction By Weight: <5%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:MODERATE IRRIT.PROLONG/REPEAT EXPO
TO LIQ MAY EXERT DERFATTING/DRYING ACTIN,RESULTING IN DERM.
INHAL:RESP IRRIT,HEADACHE,NAU,DIZZ,ANESTHETIC EFFORTS/OTHER TEMP
CNS EFFECTS.SEVERITY EFFECTS DEPEND UPON VAP CONCEN/SEVERITY OF
EXPO. INGEST:HARMFUL.
Explanation of Carcinogenicity:PER MSDS:CONTAINS METHYLENE CHLORIDE,
LISTED BY NTP AS SUBSTANCE WHICH IS "REASONABLY ANTICIPATED" TO
CAUSE CANCER.
Effects of Overexposure:SEVERAL CHRONIC INHAL STUDIES REPORTED BY NIOSH
REVEALED THAT TEST ANIMALS EXPO TO METHYLENE CHLORIDE CONCEN AS
HIGH AS 10000PPM SHOWED SLIGHT LIVER/KIDNEY CHANGES.ADMIN VIA INHAL
OVEREXPO RESULTED IN INCR INCIDENCES OF BRONCHIAL/LIVER
CARCINOMAS.
Medical Cond Aggravated by Exposure:EXPOSURE MAY AGGREAVATE
PRE-EXISTING SKIN/EYE &/OR RESP DISORDERS.

First Aid:EYE:IMMED FLUSH THOROUGHLY W/WATER FOR @LEAST 15MINS OPENING
EYELIDS.GET IMMED MED ATTN. SKIN:REMOVE CONTAMIN CLOTH.FLUSH AREA
THOROUGHLY W/PLENTY OF WATER.FOLLOW BY WASHING W/SOAP/WATER.IRRIT
PERSIST S GET MED ATTN. INHAL:REMOVE VICTIM TO FRESH AIR.PROVIDE
OXY IF BREATH DIFFI.GIVE ART RESP IF NOT BREATH.GET IMMED MED ATTN.
INGEST:DO NOT INDUCE VOMIT.CONSC/ALERT DILUTE BY GIVING WATER TO
DRINK(SUP)

Flash Point:NON-FLAMM(SUPPL)
Lower Limits:N/ESTABLISHE
Upper Limits:N/ESTABLISHE
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:SHOULD WEAR +PRESS SCBA & FULL PROT EQPMT.COOL
EXPO CNTNRS W/WATER TO PREVENT PRESSURE BUILDUP.LG QUANT INVOLVED
EVACUATE AREA,FIGHT FIRE FRM SAFE DISTANCE.
Unusual Fire/Explosion Hazard:DECOMPO/COMBUST PRODUCTS MAY BE
TOXIC.CLSD CNTNRS WILL VIOLENTLY RUPTURE UNDER FIRE CONDITIONS.

Spill Release Procedures:OPERATIONS MUST BE CONDUCTED IAW OSHA
29CFR1910.120.REVIEW MSDS BEF PROCEEDING W/SPILL RESPONSE.START
EXHAU VENTI.WIPEUP/ABSORB W/VERMI/OTHER SIMILAR MATL.WASH W/SOAPY
WATER.COLLECT/DISPOSE.SHUTOFF RE LEASE W/O RISK.DIKE/PREVENT INTO
SEWERS/ETC.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL DRY LOCATION W/ADEQUATE
VENTILATION.KEEP CNTNR TIGHTLY SEALED WHEN NOT IN USE.DO NOT STORE
NEAR HEAT/SPARKS/OPN FLAME.
Other Precautions:DELIBERATE CONCEN & INHAL OF VAP/INHAL OF VAP
DIRECTLY FRM AEROSOL CNTNR MAY BE FATAL.DO NOT REUSE CONTAMIN CLOTH
TIL PROPERLY CLEANED.

Respiratory Protection:USE APPROPRIATE,PROPERLY FITTED RESPIRATOR IF
EXPOSURES EXCEED PEL/TLV VALUES.TYPE OF RESP PROTECTION SELECTED
WILL DEPEND UPON CONDITIONS OF USE.OBSERVE OSHA REG FOR RESP
PROTECTION (29CFR1910.134).
Ventilation:EXPLOSION-PROOF MECH EXHAU VENTI-DRAWS VAP/MIST/FUMES FRM
WORK.SUFFICIENT TO MAINTIAN AIRBORNE CONCEN BELOW PEL/TLV.
Protective Gloves:PROTECTIVE GLOVES.
Eye Protection:SPLASH-PROOF CHEM GOGG,FACE SHIELDS.
Other Protective Equipment:USAGE CONDITIONS WILL VARY DEPENDING ON
APPLICATION,SPEC SAFE HDNGL PROCEDURES DEVELOPE FOR USAGE
CONDITIONS/EQPMT.(SUP)
Work Hygienic Practices:TRAIN WORKER IN SAFE HDNLG BEF USAGE.WASH
NORMAL WORKCLOTH BEF REUSE.WASH HANDS/FACE WELL AFT HDNLG BEF
SMOKE/EAT/DRINK.
Supplemental Safety and Health
FPT:GIVEN FOR AEROSOL SPRAY,BASED ON PRESENCE OF FREON/METHYLENE
CHLORIDE,SILICONE RESIN FPT >200F.DECOMP PROD HAZ:BY-PRDUCTS WILL
VARY WIDELY DEPENDING ON CONDITIONS OF COMBUST. OTHER PROT
EQPMT:CHEM =RESIST APRON,IMPERV CLOTH,EMERG EYEWASH,SAF SHOWER.
1STAID:GET IMMED MED ATTN.NEVER ANYTHING BY MOUTH IF UNCONS/CONVUL.

HCC:V2
Boiling Pt:B.P. Text:N/DETERMINE
Vapor Pres:>1.5 ATM
Vapor Density:>AIR
Spec Gravity:1.0-1.2 COATING
Solubility in Water:INSOLUBLE.
Appearance and Odor:CLEAR LIQUID, AEROSOLIZED.
Percent Volatiles by Volume:>95

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/STRONG OXIDIZERS, ACIDS, BASES.
Stability Condition to Avoid:AVOID STORAGE IN OPN CNTNRS,EXPO TO OPN
FLAME & INCOMPAT MATL,UNCONTROLLED EXPO TO HEAT,UNCONTROLLED MIX
W/CURING AGENTS
Hazardous Decomposition Products:CO,CO2,ALDEHYDES,CHLORINE
CMPDS,PHOSGENE,ACIDS,OTHER ORG SUB MAY FORM DURING COMBUST.CHEM
NATURE/QUANT OF DECOMPO (SUPP)

Waste Disposal Methods:DISPOSE OF IAW CURRENT FED/STATE/LOC REGS.
CONTAINS SARA SEC 313 CHEM:METHYLENE CHLORIDE.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.